HUNTERTUTORING

Bioorganic chemistry

Graduate · Chemistry

Syllabus focus

Standard syllabus · STEM / applied

Pricing

Graduate-level rates are set on consultation. See the pricing page for K–12 and undergraduate rates.

Topics typically covered

Standard syllabus

Peptide and protein chemistry

  • Solid-phase peptide synthesis: Fmoc and Boc strategies
  • Protecting group chemistry for amino acid side chains
  • Native chemical ligation and expressed protein ligation
  • Protein folding thermodynamics and kinetics
  • Unnatural amino acids and genetic code expansion
  • Post-translational modifications: glycosylation, phosphorylation, ubiquitination
  • Chemical probes for protein function
  • Activity-based protein profiling (ABPP)
  • Stapled peptides and peptide mimetics
  • Proteomics sample preparation and mass spectrometry

Nucleic acid chemistry

  • Phosphoramidite DNA/RNA synthesis
  • Modified nucleotides for therapeutics and diagnostics
  • CRISPR chemistry: guide RNA and Cas9 mechanism
  • Antisense oligonucleotides and siRNA
  • DNA damage and repair chemistry
  • G-quadruplexes and non-canonical structures
  • Click chemistry for nucleic acid labeling
  • Ribozymes and deoxyribozymes
  • Aptamer selection (SELEX) and applications
  • Epigenetic modifications: 5-methylcytosine, hydroxymethylation

Enzyme mechanism and inhibition

  • Active site architecture and catalytic residues
  • Covalent vs non-covalent enzyme inhibition
  • Mechanism-based (suicide) inhibitors
  • Transition state analog inhibitors
  • Allosteric regulation and cooperativity models
  • Cofactor chemistry: PLP, thiamine pyrophosphate, biotin
  • Radical SAM enzymes and radical mechanisms
  • Metalloenzyme mechanisms: zinc, iron, copper enzymes
  • Kinase inhibitors in drug discovery
  • Protease inhibitors: HIV protease, caspases

Chemical biology tools

  • Bioorthogonal chemistry: click reactions in cells
  • Photopharmacology and caged compounds
  • Fluorescent probes and biosensors
  • Chemogenomics and target identification
  • Metabolic labeling and flux analysis
  • Glycobiology: glycan synthesis and profiling
  • Lipidomics and lipid chemical biology
  • Chemical inducers of dimerization
  • DNA-encoded libraries for screening
  • Ethical considerations in chemical biology research

STEM / applied

Laboratory and research methods

  • Peptide synthesis and HPLC purification
  • Enzyme kinetics assays and IC₅₀ determination
  • Cell-based assays for chemical probes
  • Mass spectrometry for protein identification
  • NMR of biomolecules: assignment strategies
  • X-ray crystallography of protein–ligand complexes (data interpretation)
  • Molecular docking and structure-based design
  • Chemical synthesis of bioactive natural products
  • Literature analysis of bioorganic papers
  • Grant writing for chemical biology projects

Applied bioorganic chemistry

  • Antibody–drug conjugates (ADCs) linker chemistry
  • Stapled peptide therapeutics in clinical trials
  • mRNA vaccine chemistry and lipid nanoparticles
  • CRISPR therapeutic delivery chemistry
  • Biosimilar and biologic drug development
  • Agricultural bioorganic chemistry: herbicide targets
  • Industrial enzyme engineering and directed evolution
  • Diagnostics: ELISA, lateral flow, molecular beacons
  • Startups in chemical biology and biotech
  • Career paths in pharma, biotech, and academic chemical biology

Notes

Graduate-level bioorganic chemistry. Topics reflect common bioorganic chemistry syllabi at US research universities. Strong organic chemistry and biochemistry background required.